Heat a large skillet or frying pan over medium heat. Spray the skillet with olive oil cooking spray to prevent sticking.
Once the skillet is hot, add the peeled and deveined shrimp to the skillet in a single layer. Make sure the shrimp are not overcrowded in the pan to ensure even cooking.
Season the shrimp with Cajun seasoning, salt, and pepper to taste. You can adjust the amount of Cajun seasoning depending on your desired level of spiciness.
Cook the shrimp for about 2-3 minutes on one side until they start to turn pink and opaque.
Flip the shrimp over with tongs and cook for an additional 2-3 minutes on the other side until they are fully cooked through and opaque.
Be careful not to overcook the shrimp, as they can become tough and rubbery if cooked for too long.
Once the shrimp are cooked through, remove the skillet from the heat.
Serve the stove-top shrimp immediately, garnished with optional lemon wedges and chopped parsley if desired.